The MPI-Mainz UV/VIS Spectral Atlas

of Gaseous Molecules of Atmospheric Interest

www.uv-vis-spectral-atlas-mainz.org

Hannelore Keller-Rudek1, Geert K. Moortgat2, Rolf Sander2, Rüdiger Sörensen1

1Satellite Group

2Atmospheric Chemistry Division

Max-Planck Institute for Chemistry
Mainz, Germany

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When referring to the Spectral Atlas, please cite our publication:

Keller-Rudek, H., Moortgat, G. K., Sander, R., and Sörensen, R.: The MPI-Mainz UV/VIS spectral atlas of gaseous molecules of atmospheric interest, Earth Syst. Sci. Data, 5, 365–373, (2013), DOI: 10.5194/essd-5-365-2013

Cross Sections / Unclassified / VCl4 / IversonRussell(1973)_298K_120.5-197.0nm(max)

DATAFILE: VCl4_IversonRussell(1973)_298K_120.5-197.0nm(max).txt
NAME: vanadium tetrachloride
FORMULA: VCl4
AUTHOR(YEAR): IversonRussell(1973)
T: 298K
λ: 120.5-197.0nm(max)
BIBLIOGRAPHY: A.A. Iverson and B.R. Russell, "Electronic spectra of TiCl4, VCl4, and SnCl4 in the vacuum ultraviolet", Spectrochim. Acta A: Mol. Spectrosc. 29, 715-723 (1973); DOI: 10.1016/0584-8539(73)80101-1
COMMENTS: Maxima of the high-resolution (∼0.058 nm) absorption spectrum recorded using a discharge lamp with a small flow of H2

Extinction coefficients from Table 2 have been converted to absorption cross sections (conversion factor 3.8235×10-21)

Absorbances vs. wavelength are shown in Fig. 4 (115-210 nm)

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